Measure sf polygon as line segments

I want to return the dimensions of some gridded polygons. I know the overall area of the polygons, but I would like to have the height and width as well for some calculations. The polygons are sf objects and I wanted to convert them into multiline objects and then just take the length of each line. I can't figure out how to do this, but assume there is a built in function in the sf package for this.

For some sample code:

nc <- st_read(system.file("shape/nc.shp", package="sf"))
poly <- nc[5,] # object five chosen at random for testing

Now I just want poly to be converted to a series of lines, and then be able to take the length of those lines.

Any help is appreciated.